Those reductions occur at different times (the Defensive Stance and Armor).
Defensive Stance reduction is handled before everything else, a straight 10% off the incoming damage. Armor is calculated after it. More importantly, Shield Block is calculated after it (and Armor) so you always get the full effect from a block and blocks become pretty overpowered in some places.
There IS a hard cap of 75% mitigation from Armor. It will be a very, very long time before anyone reaches it. The only times I reached it were a handful of times in Naxxramas with every possible buff (Loatheb, for instance) and Lay On Hands, etc. procs. That kind of mitigation makes you essentially unkillable., because you then factor in your avoidance/block/defensive stance/etc., and suddenly mobs that would destroy most people can barely scratch you if you have good healers.
The Auto Blocker... a total of 59 additional block value? or the On Equip bonus was raised to meet that? Either way, very good!
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